Electronic structure and fluorescence spectra of HeO+ cation.
A.N.Petrov1 and A.I.Panin2
1PNPI RAS, St.Petesburg, Gatchina, 188350 Russia
2Research Inst. of Chemistry, St.Petersburg State University, St.Petersburg, 198904 Russia
Quantum-mechanical calculations of the potential curves of the HeO+ ion are performed wich correlate with four lower dissociation limits and indicate the excimer type of the ion. The transition dipole moments of the 22S -®12S - and 24S -®14S - transitions are calculated. The energies and radiative lifitimes of vibrational levels are determined and structural and spectroscopic constants of the states 12S -, 22S -, 24S -, and 24S - are calculated. The fluorescence spectrum corresponding to the 22S -®12S - and 24S -®14S - transitions is also calculated. The possibility of lasing at these transitions is discussed.